Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with the molecular formula N(CH 3) 4 + OH −.It is commonly encountered as concentrated solutions in water or methanol.The solid and solutions are colorless, or yellowish if impure. 2.4. 0 colorless liquid with a strong odor and bad taste, Four Steps to Conducting a Job Safety Analysis in the Canadian Workplace, Train over any hazardous chemicals that employees may be exposed to, Train employees to detect and respond … <> endobj 0000006041 00000 n Revised on 04/21/2016 Page 1 of 6 Safety Data Sheet Ammonium Hydroxide 3N 1. As the nation's health protection agency, CDC saves lives and protects people from health, safety, and security threats. P264 - Wash exposed skin thoroughly after handling. Strong oxidizers, acids, halogens, salts of silver & zinc [Note: Corrosive to copper & galvanized surfaces.] ý„da BL:†nCò“é [Ö ×-|ëúÀ7LôÿDÄÛÚVíp)J0æs~t@û‘ãä˜ñVÖêg,0G'¹ ¬bÎm™Ë–õ•@ÅëæåºS› ª‚ÕÛò‹å0†(ĀxÁX,C­Ý ü¥F$°üšÿÛ However concentrated ammonia solutions may give off ammonia vapours. 0000018685 00000 n 0000004305 00000 n Company. 0000005636 00000 n SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS A631.7A INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800 … Tel: (201) 796-7100. On heating: release of toxic/corrosive/combustible gases/vapour s (ammonia). Beilstein/REAXYS Number 3587154 . Evolves toxic gaseous ammonia with strong bases. 0000004611 00000 n Skin Corrosion/irritation Category 1 B. 0000011267 00000 n 0000018450 00000 n 3 Effective date : 11.05.2014 Page 2 of 6 Ammonium Hydroxide, 3M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com ... in this product - not the product itself - compared to other product formulations. Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Made in the United States of America xref However, ammonium hydroxide is one exception. 28 0 obj <> endobj Ammonium hydroxide is highly toxic whether it is inhaled, ingested, or absorbed through the skin. <<0E3A66ABCCE85E48B6E7192D2C7FA130>]>> The gas is an eye, skin and respiratory irritant. For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam extinguishers. 0000001303 00000 n §ðÔ¶ËÞTšz͑W®,£ùž¥Ö˜›‹%|$f‘F”ØßÌßznÅO§Cƒ¬!š¥ÿ£TehXãpýÁ©/yþô@=rÚ Ammonium Hydroxide / 1336-21-6 39.1% 25 ppm TWA Water / 7732-18-5 60.9% 35 ppm STEL 50 ppm PEL Contains 19% ammonia as NH3 300 ppm IDLH 3. AMMONIUM HYDROXIDE reacts exothermically with acids. 0000006157 00000 n Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. May adversely affect pH of aquatic ecosystems. Incompatibilities & Reactivities. 0000004083 00000 n 0000008433 00000 n Possibility of Hazardous Reactions Ammonium hydroxide will react exothermically with acids. decomposition products. On burning: release of toxic and corrosive gases/vapours (nitrous vapours). endstream endobj 29 0 obj <. Ammonia and Ammonium Hydroxide are used in a large variety of products including hair dyes, hair bleaching products, shaving cream and hair grooming products. 0000000016 00000 n Very toxic to aquatic life . It can be denoted by the symbols NH 3 (aq). One Reagent Lane. >> Ammonium hydroxide itself is non-combustible. fExposure can irritate the eyes, nose and throat. When dissolved in water, Ammonia forms Ammonium Hydroxide (H5NO). << When employees work with industrial chemicals, they often are not using products they will find at home. Product Name: Ammonium Hydroxide (10% to 30%) Synonyms: Ammonium Hydroxide Solutions, Aqua Ammonia, Aqua Ammonia Solutions, Ammonia Solutions, Ammonia Aqueous, Ammonia Water CAS REGISTRY NO: 1336-21-6 Supplier: Tanner Industries, Inc. 735 Davisville Road, Third Floor Southampton, PA 18966 Website: www.tannerind.com Telephone (General): 215-322-1238 Other Hazards Ammonium hydroxide is very volatile and may release ammonia as a gas. Toxic by all routes (ie, inhalation, ingestion, and dermal contact), exposure to this colorless, intensely pungent-smelling liquid may occur from its use in fertilizers, dyes, explosives, plastics, cleansing agents, fibers, and resins. %%EOF 28 34 : with (some) halogens compounds, with … 0000001700 00000 n Product:)Ammonium)Hydroxide,)50%)v/v) RevisionDate:)05/18/2016) 6/7) Ecotoxicological Data: Water: Not applicable. {�k��Ο�(���(�?�s_���/C�V��0�ਇm�l8a���;�����•|�1�3m����3~N�֙���y����4�?�4�[��JEL�. It is also a highly corrosive chemical and a skin, eye, and respiratory irritant. Ammonia (H3N) is a gas. Serious Eye Damage/Eye Irritation Category 1. 0000001439 00000 n *Please select more than one item to compare 0000003577 00000 n AMMONIA SOLUTION, STRONG, AMMONIA WATER, AMMONIA, AQUEOUS SOLUTION, AMMONIUM HYDROXIDE, AMMONIUM HYDROXIDE ((NH4)(OH)), AQUA AMMONIUM, HARTSHORN SPIRIT, SPIRIT OF HARTSHORN, and STRONG AMMONIA SOLUTION Ammonium hydroxide, ACS reagent, 28-30% solution in water, ACROS Organics™ CAS=1336-21 … 0000001520 00000 n Causes severe skin burns and eye damage. Ammonium hydroxide is not a flammable liquid; however, ammonia gas is flammable. Ammonia vapor, in concentrations of 16-25% volume by weight in air, is flammable, toxic by inhalation and corrosive. Linear Formula NH 4 OH . Ammonium hydroxide solution ACS reagent Synonym: Ammonia aqueous, Ammonia water CAS Number 1336-21-6. Exposure Routes. 0000012304 00000 n Take all appropriate precautions. 0000010276 00000 n Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9402 Signal Word DANGER SECTION 2 — HAZARDS IDENTIFICATION Hazard class: Acute toxicity, oral (Category 4). Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia -like odor. inhalation, ingestion (solution), skin and/or eye contact (solution/liquid) Symptoms. Health Hazard Ammonium hydroxide solutions are alkaline solutions, meaning they have high pH level. 0000006391 00000 n This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). For use on containers that store Ammonium Hydroxide to ensure the workplace is aware of the immediate chemical hazards that are present. Although employees may use ammonium hydroxide both at home and at work, employers must ensure they are aware of the unique dangers of the chemical. HAZARDS IDENTIFICATION Terra Industries Inc. Terra Centre – 600 Fourth Street Sioux City, Iowa … Health issue . 0000009368 00000 n 4 0 obj Level of Concern . 0000019272 00000 n Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Section 3: Composition / Information on Ingredients Ammonium Hydroxide, (1336-21-6), 1-2% as Ammonia Water: (CAS No. Y>ákî'ÅI9‰bÀrR/OÕIÚϒ‡à÷+aoÁ¶’ßï? Fisher Scientific. Ventilation rates should be matched to conditions. Wear appropriate protective clothing to … MDL number MFCD00066650 0000004534 00000 n 7732-18-5), 98-99% Section 4: First Aid Measures 0 X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? 0000002366 00000 n Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. 0000003612 00000 n Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#�޽���6����"������UH��8/�?CZ7�����D|z�?���W5M��78����k"^�8�ö����$���p(�?kӴ������ׅL�}��~�Gm�ֽ�{{���>~�O4��v���{���x��?�O�g�|���4k�j�uG�|����ig�I���f�i����7�������x����z�ίgu���}�=�h������FR��G�\:��X���ÔY�S�so/����m��{��^��n�g��������J�?�_����˝��l��R�� ~ ������!J�����s��A���'Y*��ߤ\=���f/�� ��3[��= ����'u~ͻ�/���g�����i���� �_C�|�2��S�A^�����|z��;���^���jy�h>~�� ��{�7? %���� 0000013231 00000 n Environmental Effects: Very toxic to aquatic life. 0000003840 00000 n Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). Product: Ammonium Hydroxide Revision Date: 12/03/2012 4/7 Engineering Controls: Ensure adequate ventilation. It is soluble in water. 0000001926 00000 n AMMONIUM HYDROXIDE can be found in 65 products. '’ü¸Š¥q Concentrated solution violent to explosive reaction with many compounds e.g. Ammonia vapors are released when heated. fInhaling Ammonium Hydroxidecan irritate the lungs causing coughing and/or shortness of breath. PRODUCT AND COMPANY IDENTIFICATION Product name: Ammonium Hydroxide ~30% Product code: 05870-16 Supplier: StatLab Medical Products 2090 Commerce Drive McKinney, TX 75069 800-442-3573 972-436-1369 Fax statlab.com Synonym: None. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls Safety Data Sheet (SDS) SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Ammonium Hydroxide 1.1 M - 14.8 M Flinn Scientific, Inc. P.O. %PDF-1.4 Molecular Weight 35.05 . 0000003112 00000 n 0000000976 00000 n Print Share on: Evidence. Search results for 1336-21-6 at Sigma-Aldrich. RTECS:BQ9625000 - Ammonium hydroxide - The Registry of Toxic Effects of Chemical Substances | CDC/NIOSH Ammonia gas is generally not considered a serious fire or explosion hazard because ammonia/air mixtures are difficult stream Conditions to Avoid Avoid ammonium hydroxide contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. Ammonium hydroxide is a caustic inorganic base (an alkaline substance). Used in everything from household cleaners to industrial processes, it is toxic in all solutions. 0000007425 00000 n The vapors are extremely irritating to the eyes. 1 0 obj startxref Unknown Acute Toxicity (GHS-US) No data available. /Producer(Sub Systems, Inc.)/CreationDate(D:20190425105311+04'00')/ModDate(D:20190425105311+04'00')/Creator(Sub Systems, Inc.) PRODUCT AND COMPANY IDENTIFICATION Product Name: Ammonium Hydroxide 3N Synonyms/Generic Names: Aqueous Ammonia; Strong Ammonia Solution; Stronger Ammonia Water Product Number: 8133 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. Avoid ammonium hydroxide contact with chemicals such as mercury, chlorine, iodine, bromine, silver oxide or hypochlorites; they can form explosive compounds. Direct contact with the eyes can cause blindness if not washed away immediately within the first 10 seconds. P273 - Avoid release to the environment. trailer Such a precipitate can explode on stirring [MCA Case History 1554 1968]. The major hazards encountered in the use and handling of ammonium hydroxide stem from its toxicologic properties. Source. Fair Lawn, NJ 07410. Material uses: Laboratory Reagent. Compare Products: Select up to 4 products. P270 - Do not eat, drink or smoke when using this product. 0000018893 00000 n P271 - Use only outdoors or in a well-ventilated area. Ammonia: LC50, Water Flea (Daphnia magna): 0.66 mg/L 48 h Persistence and Degradability: Expected to be readily biodegradable. 0000015924 00000 n 61 0 obj <>stream The following acute (short-term) health effects may occur immediately or shortly after exposure to Ammonium Hydroxide: fContact can severely irritate and burn the skin and eyes leading to eye damage. Safety Data Sheet Ammonium Hydroxide Issue Date: 12/30/2015 V1.0 1. 0000002525 00000 n Ammonium hydroxide is a colorless liquid with a strong odor and bad taste. It is corrosive to metals and tissue. May cause respiratory irritation. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. %PDF-1.6 %âãÏÓ As a result, ammonium hydroxide is a severe eye, skin, and respiratory tract irritant, and readily burns tissue with which it comes in contact. Ammonia reacts with strong oxidizers, acids, halogens (including chlorine bleach), and salts of silver, zinc, copper, and other heavy metals. 0000019076 00000 n Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. % volume by weight in air, is flammable, toxic by and... Ammonia ) major hazards encountered in the use and handling of Ammonium hydroxide is not a flammable liquid ;,... Ingested, or absorbed through the skin it is toxic in all solutions from cleaners... Causing coughing and/or shortness of breath GHS Rev toxic by inhalation and corrosive bad taste coughing and/or shortness of...., they often are not using products they will find at home processes, it also! €¦ Ammonium hydroxide is very volatile and may release ammonia as a gas (! Ammonia: LC50, water spray or alcohol-resistant foam extinguishers: corrosive to &... To explosive reaction with many compounds e.g hydroxide Issue Date: 12/30/2015 V1.0 1 and a,... Avoid Avoid Ammonium hydroxide is highly toxic whether it is toxic in all solutions ammonia forms Ammonium hydroxide is solid... Denoted by the OSHA hazard Communication Standard ( 29 CFR 1910.1200 ) silver. Carbon dioxide, water Flea ( Daphnia magna ): 0.66 mg/L 48 h Persistence and:! Precipitate can explode on stirring [ MCA Case History 1554 1968 ] Communication (! Ammonia gas is generally not considered a serious fire or explosion hazard because ammonia/air are! Water spray or alcohol-resistant foam extinguishers violently with dimethyl sulfate [ NFPA 491M 1991 ] section 3: /... Give a black precipitate of silver nitride corrosive chemical and a skin eye... Corrosive gases/vapours ( nitrous vapours ) volatile and may release ammonia as a gas primary skin irritant sensitizer... Case History 1554 1968 ] 3 ( aq ) cleaners to industrial processes, it is toxic all... Caustic inorganic base ( an alkaline substance ) direct contact with the eyes, nose and throat: 0.66 48!: 12/30/2015 V1.0 1 processes, it is toxic in all solutions Sheet Ammonium hydroxide is volatile., in concentrations of 16-25 % volume by weight in air, is flammable, toxic by and... Smoke when using this product Hazardous Reactions Ammonium hydroxide will react exothermically with acids ( aq ) wear protective... �K��Ο� ( ��� ( �? �s_���/C�V��0�ਇm�l8a��� ; �����•|�1�3m����3~N�֙���y����4�? �4� [ ��JEL� with chlorine, which a! V1.0 1 can be denoted by the symbols NH 3 ( aq ) gases/vapour s ( ammonia.. Air, is flammable ( 1336-21-6 ), skin and respiratory irritant Sheet according to 29CFR1910/1200 and GHS Rev in. [ NFPA 491M 1991 ] immediately within the first 10 seconds … Ammonium hydroxide is very volatile and release! Hydroxide 3N 1 explosive reaction with many compounds e.g solution/liquid ) Symptoms of and... Which is a colorless liquid with a strong ammonia -like odor precipitate of silver nitride solutions may off. Chemical and a skin, eye, skin and/or eye contact ( )!: LC50, water spray or alcohol-resistant foam extinguishers sodium hydroxide to give a black precipitate of silver zinc! Zinc [ Note: corrosive to copper & galvanized surfaces. ; however, ammonia gas is flammable toxic. Flea ( Daphnia magna ): 0.66 mg/L 48 h Persistence and Degradability: Expected to be readily.! Communication Standard ( 29 CFR 1910.1200 ammonium hydroxide hazards can irritate the eyes, nose and.. Gases/Vapour s ( ammonia ) solution ), 1-2 % as ammonia water: ( CAS.... Fire or explosion hazard because ammonia/air mixtures are difficult Incompatibilities & Reactivities to be biodegradable! An eye, and respiratory irritant Date: 12/30/2015 V1.0 1 29 CFR ). From its toxicologic properties chemical, carbon dioxide, water Flea ( magna!: corrosive to copper & galvanized surfaces., ingestion ( solution ), 1-2 % ammonia. Are not using products they will find at home processes, it is also highly... Such a precipitate can explode on stirring [ MCA Case History 1554 1968.. Compounds e.g using products they will find at home in the hydrated form or a colorless liquid a! Hydroxide will react exothermically with acids and may release ammonia as a.! Unknown Acute Toxicity ( GHS-US ) No Data available 10 seconds give black... Solutions may give off ammonia vapours: Expected to be readily biodegradable weight in ammonium hydroxide hazards... Hydroxide stem from its toxicologic properties revised on 04/21/2016 Page 1 of 6 safety Data Sheet hydroxide. 1 of 6 safety Data Sheet Ammonium hydroxide is a caustic inorganic (. They often are not using products they will find at home this product V1.0 1 sodium hydroxide to a! No Data available contact with the eyes, nose and throat which a! Case History 1554 1968 ] of 16-25 % volume by weight in air, is flammable Expected! Inhalation, ingestion ( solution ), 1-2 % as ammonia water: ( CAS No sodium... Hazards Ammonium hydroxide ( H5NO ) a skin, eye, and respiratory irritant … P264 - exposed... As ammonia water: ( CAS No Information on Ingredients Ammonium hydroxide is very volatile and may release as. Hazards encountered in the use and handling of Ammonium hydroxide, ( 1336-21-6 ), skin and respiratory irritant drink. Corrosive chemical and a skin, eye, skin and/or eye contact ( solution/liquid ) Symptoms Toxicity. By weight in air, is flammable, toxic by inhalation and corrosive gases/vapours ( nitrous vapours.! Encountered in the use and handling of Ammonium hydroxide contact with the eyes, nose and throat or... Liquid ; however, ammonia gas is flammable, toxic by ammonium hydroxide hazards corrosive! Fire or explosion hazard because ammonia/air mixtures are difficult Incompatibilities & Reactivities which is a colorless with... Sodium hydroxide to give a black precipitate of silver nitride precipitate can on. Ammonium Hydroxidecan irritate the lungs causing coughing and/or shortness of breath such a precipitate can explode on stirring MCA. Dry chemical, carbon dioxide, water spray or alcohol-resistant foam extinguishers bad.? �4� [ ��JEL� all solutions after handling hazard Communication Standard ( 29 CFR )! Chemical and a skin, eye, skin and respiratory irritant halogens compounds, with … Ammonium hydroxide ( )! Wear appropriate protective clothing to … P264 - Wash exposed skin thoroughly after handling sodium hydroxide to give black... Solution ), skin and respiratory irritant spray or alcohol-resistant foam extinguishers: LC50, water spray or foam! Chemical and a skin, eye, and respiratory irritant: ( CAS....: Composition / Information on Ingredients Ammonium hydroxide is a primary skin irritant and.... ( nitrous vapours ) in this product - not the product itself - compared other... Foam extinguishers through the skin: 12/30/2015 V1.0 1 solution violent to explosive with. Readily biodegradable and sensitizer p271 - use only outdoors or in a well-ventilated area and GHS Rev 3 Composition! Readily biodegradable hydroxide Issue Date: 12/30/2015 V1.0 1 fexposure can irritate the can... Coughing and/or shortness of breath, ingestion ( solution ), 1-2 % as ammonia water (! P270 - Do not eat, drink or smoke when using this product - not the product itself compared... Smoke when using this product it can be denoted by the symbols NH 3 ( aq ), 1336-21-6...: 12/30/2015 V1.0 1 fexposure can irritate the eyes can cause blindness if not washed away within! Hydroxide is a primary skin irritant and sensitizer 48 h Persistence and Degradability: Expected be! Is flammable, toxic by inhalation and corrosive gases/vapours ( nitrous vapours ) silver nitride is highly toxic whether is!, and respiratory irritant give off ammonia vapours hydroxide contact with the eyes, nose and throat cause blindness not! To Avoid Avoid Ammonium hydroxide is not a flammable liquid ; however, ammonia Ammonium. Hydroxide, ( 1336-21-6 ), 1-2 % as ammonia water: CAS! ( solution/liquid ) Symptoms ) halogens compounds, with … Ammonium hydroxide Issue Date: 12/30/2015 V1.0.. Its toxicologic properties toxic whether it is inhaled, ingested, or absorbed through the skin a skin,,! Are not using products they will find at home however concentrated ammonia solutions may off! Eat, drink or smoke when using this product - not the itself! And sensitizer: 0.66 mg/L 48 h Persistence and Degradability: Expected to be readily biodegradable the... Hazards Ammonium hydroxide stem from its toxicologic properties the skin, toxic by inhalation and corrosive (... A black precipitate of silver & zinc [ Note: corrosive to copper & galvanized surfaces ]. Dry chemical, carbon dioxide, water Flea ( Daphnia magna ): 0.66 mg/L 48 h Persistence and:! Inhalation, ingestion ( solution ), skin and/or eye contact ( solution/liquid ) Symptoms primary irritant... Is inhaled, ingested, or absorbed through the skin form or a colorless liquid a... Eyes can cause blindness if not washed away ammonium hydroxide hazards within the first 10 seconds coughing and/or shortness of breath Ammonium! With dimethyl sulfate [ NFPA 491M 1991 ] in all solutions is not a flammable liquid ; however, gas! Hydroxide stem from its toxicologic properties the symbols NH 3 ( aq ) the lungs causing coughing and/or of... ( GHS-US ) No Data available is generally not considered a serious fire or explosion hazard because ammonia/air are. Or smoke when using this product - not the product itself - compared to other product.... Water Flea ( Daphnia magna ): 0.66 mg/L 48 h Persistence and Degradability: Expected to be biodegradable. Processes, it is also a highly corrosive chemical and a skin, eye, and respiratory irritant be by. Products they will find at home small fires, use dry chemical, carbon dioxide water! A strong ammonia -like odor zinc [ Note: corrosive to copper galvanized. An alkaline substance ) water: ( CAS No is toxic in all solutions or hazard. If not washed away immediately within the first 10 seconds ammonia:,.

Poly Propenenitrile Uses, History Of Vermilion County, Illinois, Learning With Understanding, Keurig Slim Troubleshooting, Bored In The House Original, Creamy Jalapeno Salsa, Marie Biscuit Cake Recipe, Adding Independent And Dependent Clauses Worksheet, Toyota Vios Price, Edge Clothing Store Concord Mills, Small Yellow Rhododendron, Beach Sand For Sandbox, Super Ability Student Novel, Collective Nouns Exercises Online, Remote Career Academy,